When used for purposes such as sterilization, inner packagings of peroxyacetic acid, stabilized, classified as UN 3107 Organic peroxide type E, liquid or UN 3109 Organic peroxide type F, liquid may be fitted with a vent consisting of hydrophobic membrane, provided: (1) Each inner packaging contains not more than 70 mL; (2) The inner packaging is designed so that the vent is not immersed in liquid in any orientation; (3) Each inner packaging is enclosed in an intermediate rigid plastic packaging with a small opening to permit release of gas and contains a buffer that neutralizes the contents of the inner packaging in the event of leakage; (4) Intermediate packagings are packed in a fiberboard box (4G) outer packaging; (5) Each outer packaging contains not more than 1.4 L of liquid; and. 200 Division 1.4G consumer fireworks may be certified for transportation by a DOT-approved Fireworks Certification Agency in accordance with the provisions of 173.65 of this subchapter. . The coal tar pitch compound must be in a solid mass during transportation. The lithium batteries must meet the requirements of 173.185(a) and contain the necessary systems to prevent overcharge and over discharge between the batteries. formatting. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. A11 For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used. (iii) A copy of the test results must be kept on file at each facility where packagings are offered for transportation, and must be made available to a representative of the Department upon request. 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. Use the navigation links in the gray bar above to view the table of contents that this content belongs to. For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1408, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N, of this subchapter. Shipping papers at all times must reflect a correct current accounting of all cylinders both full and expended. B8 Packagings shall be made of nickel, stainless steel, or steel with nickel, stainless steel, lead or other suitable corrosion resistant metallic lining. B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. Data collection and handling. A rocket motor to be considered nonpropulsive must be capable of unrestrained burning and must not appreciably move in any direction when ignited by any means. B67 All valves and fittings must be protected by a securely attached cover made of metal not subject to deterioration by the lading, and all valve openings, except safety valve, must be fitted with screw plugs or caps to prevent leakage in the event of valve failure. 165 These substances are susceptible to exothermic decomposition at elevated temperatures. Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in. DOT Specification 57 port-able tanks used for the transport by vessel of Class 3, Packaging Group II materials must conform to the fol-lowing: (1) Minimum design pressure. 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. 3090 or 3091, as appropriate. In addition to the packaging required in 173.4a, each glass inner packaging must be placed in a sealed plastic bag compatible with ethylene oxide and capable of containing the contents in the event of breakage or leakage of the glass inner packaging; and. 132 This description may only be used for ammonium nitrate-based compound fertilizers. 172-123, 55 FR 52582, Dec. 21, 1990]. 4 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone D (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Mixtures containing at least 98%, by mass, of phlegmatizer are not subject to the requirements of this subchapter. Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles. Only Specifications MC 304, MC 307 or DOT 407 cargo tank motor vehicles are authorized for transportation by vessel. 33 Ammonium nitrites and mixtures of an inorganic nitrite with an ammonium salt are prohibited. d. Except for transportation by aircraft, neutron radiation detectors and radiation detection systems containing such detectors transported in accordance with paragraph a of this special provision are not subject to the labeling and placarding requirements of part 172 of this subchapter. Have accident damage protection which conforms with 178.345-8 of this subchapter; c. Have a MAWP or design pressure of at least 87 psig: and. IBCs of type 31A and 31N are only authorized if approved by the Associate Administrator. 70 Black powder that has been classed in accordance with the requirements of 173.56 of this subchapter may be reclassed and offered for domestic transportation as a Division 4.1 material if it is offered for transportation and transported in accordance with the limitations and packaging requirements of 173.170 of this subchapter. 30 Sulfur is not subject to the requirements of this subchapter if transported in a non-bulk packaging or if formed to a specific shape (for example, prills, granules, pellets, pastilles, or flakes). Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). TP25 Sulphur trioxide 99.95% pure and above may be transported in tanks without an inhibitor provided that it is maintained at a temperature equal to or above 32.5 C (90.5 F). The rechargeable (and some non-rechargeable) types have gelled alkaline electrolytes (rather than acidic) making it difficult for them to generate hydrogen or oxygen when overcharged and therefore, differentiating them from non-spillable batteries. 148 For domestic transportation, this entry directs to 173.66 for: a. When a specific portable tank instruction is specified by a T Code in Column (7) of the 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if: (A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified); (B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified); (C) The alternative portable tank has a pressure relief device as specified in the T Code. Special Provision Letter Codes Used in Hazmat Table, Column 7 Column 7 uses eight letter codes. Navigate by entering citations or phrases Nickel-metal hydride batteries subject to this special provision are subject only to the following requirements: (1) The batteries must be prepared and packaged for transport in a manner to prevent a dangerous evolution of heat, short circuits, and damage to terminals; and are subject to the incident reporting in accordance with 171.16 of this subchapter if a fire, violent rupture, explosion or dangerous evolution of heat (i.e., an amount of heat sufficient to be dangerous to packaging or personal safety to include charring of packaging, melting of packaging, scorching of packaging, or other evidence) occurs as a direct result of a nickel metal hydride battery; and (2) when loaded in a cargo transport unit in a total quantity of 100 kg gross mass or more, the shipping paper requirements of Subpart C of this part, the manifest requirements of 176.30 of this subchapter, and the vessel stowage requirements assigned to this entry in Column (10) of the 172.101 Hazardous Materials Table. Symbol Meaning Which is the correct column for hazardous materials? For all modes of transportation, a written report submitted, retained, and updated in accordance with 171.16 is required if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a dry battery or battery-powered device. These detectors must have a minimum burst pressure of 1800 kPa as demonstrated by design type qualification testing; and. b. Gases of Division 2.3 and gases with a subsidiary risk of 5.1 must not be used as a propellant in a chemical under pressure. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). It may not be used to describe articles, machinery, or apparatus for which a proper shipping name exists in the 172.101 Table. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. The articles may be transported as in Division 1.4 Compatibility Group D (1.4D) if all of the conditions specified in 173.63(a) of this subchapter are met. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. 172 This entry includes alcohol mixtures containing up to 5% petroleum products. will bring you to those results. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. 8 A hazardous substance that is not a hazardous waste may be shipped under the shipping description Other regulated substances, liquid or solid, n.o.s., as appropriate. 105 The word Agents may be used instead of Explosives when approved by the Associate Administrator. (5) A code containing the letter N refers to a special provision which applies only to non-bulk packaging requirements. 441 For marine pollutants transported under UN3077, Environmentally hazardous substance, solid, n.o.s. or UN3082, Environmentally hazardous substance, liquid, n.o.s. and for purposes of shipping paper and package marking requirements, the technical name used in association with the basic description may be a proper shipping name listed in the 172.101 Hazardous Material Table; provided that the name chosen is not also an entry that includes n.o.s. as a part of the name or one that has a G in column (1) of the table. 64 The group of alkali metals includes lithium, sodium, potassium, rubidium, and caesium. Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. b. (ii) The following is a list of the portable tank special provisions: TP1 The maximum degree of filling must not exceed the degree of filling determined by the following: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. Other inorganic nitrate salts may replace part of the ammonium nitrate. Explosives shipped in conformance with this paragraph must have been examined in accordance with 173.56 of this subchapter and approved by the Associate Administrator. 49 CFR 172.101 The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions. When a special provision specifies packaging or packaging requirements -, (1) The special provision is in addition to the standard requirements for all packagings prescribed in 173.24 of this subchapter and any other applicable packaging requirements in subparts A and B of part 173 of this subchapter; and. 139 Use of the special arrangement proper shipping names for international shipments must be made under an IAEA Certificate of Competent Authority issued by the Associate Administrator in accordance with the requirements in 173.471, 173.472, or 173.473 of this subchapter. Other inorganic nitrate salts may replace part of the ammonium nitrate. g. The test results shall be documented, shall be traceable, and shall be made available to a representative of the Department upon request. Limited propagation means that if one booster near the center of the package is exploded, the aggregate weight of explosives, excluding ignition and delay charges, in this and all additional boosters in the outside packaging that explode may not exceed 25 g. 116 Fuzes, detonating may be classed in Division 1.4 if the fuzes do not contain more than 25 g of explosive per fuze and are made and packaged so that they will not cause functioning of other fuzes, explosives or other explosive devices if one of the fuzes detonates in a shipping packaging or in adjacent packages. B120 The use of flexible bulk containers conforming to the requirements in subpart R and subpart S of part 178 of this subchapter is permitted. TP7 The vapor space must be purged of air by nitrogen or other means. Batteries and battery-powered device(s) containing batteries must be prepared and packaged for transport in a manner to prevent: (2) Short circuits, including but not limited to the following methods: (i) Packaging each battery or each battery-powered device when practicable, in fully enclosed inner packagings made of non-conductive material; (ii) Separating or packaging batteries in a manner to prevent contact with other batteries, devices or conductive materials (e.g., metal) in the packagings; or, (iii) Ensuring exposed terminals or connectors are protected with non-conductive caps, non-conductive tape, or by other appropriate means; and. A copy of the approval must accompany each shipment. N42 1A1 drums made of carbon steel with thickness of body and heads of not less than 1.3 mm (0.050 inch) and with a corrosion-resistant phenolic lining are authorized for stabilized benzyl chloride if tested and certified to the Packing Group I performance level at a specific gravity of not less than 1.8. A hypochlorite solution, UN1791, is a Class 8 corrosive material. A5 Solids having an inhalation toxicity of Packing Group I are not permitted on passenger aircraft and may not exceed a maximum net quantity per package of 15 kg (33 pounds) on cargo aircraft. (You can unsubscribe anytime), Learn More About USDOT/HazMat Transportation, generalpackaging requirements of173.24, Frequently Asked Questions Regarding the Regulations of the Resource Conservation and Recovery Act.